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- WATER SUPPLY, SEWERAGE, BUILDING SYSTEMS OF WATER RESOURCES PROTECTION
- The Use Of Silver And Copper Colloid For Disinfection Of Water In Cooling Towers
- UDC 628.166-926.57
doi: 10.33622/0869-7019.2026.03.84-90
Roman A. GURDIN1, rgurdin@lan.spbgasu.ru
Andrey N. BELYAEV1, belyaev71@list.ru
Yuriy A. FEOFANOV1, ufeofanov@rambler.ru
Vladimir V. SHABALIN1, vvshabalin@mail.ru
Nikolay A. CHERNIKOV2, nika_pgups@mail.ru
1 Saint Petersburg State University of Architecture and Civil Engineering, 2-ya Krasnoarmeyskaya ul., 4, St. Petersburg 190005, Russian Federation
2 Emperor Alexander I St. Petersburg State Transport University, Moskovskiy prospekt, 9, St. Petersburg 190031, Russian Federation
Abstract. The effectiveness of a combined method of disinfection of water in cooling towers based on the use of silver and copper colloids synthesized by electrolysis, hydrogen peroxide and a sand filter is evaluated. It has been shown that this combination will provide a synergistic and prolonged antimicrobial effect. The study was conducted over eight months and included six stages. A colloid containing ions and nanoscale metal particles was generated in a flow mode using an electrolyzer with alternating electrode polarity. The analysis of the source water showed a high level of microbiological contamination. The introduction of silver and copper colloid did not lead to the expected decrease, which required the addition of an oxidizing agent, hydrogen peroxide. The subsequent installation of a sand filter saturated with keloid during operation made it possible to achieve a steady decrease in the concentrations of target microorganisms until the end of the observation. Regression analysis showed a negative correlation between the time of application of the combined system and the level of contamination, that is, the proposed scheme demonstrated effectiveness for long-term control of biofouling.
Keywords: water disinfection, cooling towers, silver and copper colloidal systems, electrochemical synthesis, hydrogen peroxide, modified sand filter - REFERENCES
1. Liu Y., Zhang W., Sileika T. et al. Disinfection of bacterial biofilms in pilot-scale cooling tower systems [Дезинфекция бактериальных биопленок в экспериментальных системах градирен]. Biofouling, 2011, no. 27, pp. 393-402.
2. Pagnier I., Merchat M., La Scola B. Potentially pathogenic amoeba-associated microorganisms in cooling towers and their control [Потенциально патогенные микроорганизмы, ассоциированные с амебами, в градирнях и способы борьбы с ними]. Future Microbiol, 2009, no. 4, pp. 615-629.
3. Yamamoto H., Ezaki T., Ikedo M., Yabuuchi E. Effects of biocidal treatments to inhibit the growth of Legionellae and other microorganisms in cooling towers [Воздействие биоцидных обработок на подавление роста легионелл и других микроорганизмов в градирнях]. Microbiol. Immunol, 1991, no. 35, pp. 795-802.
4. Breiman R. F. Impact of technology on the emergence of infectious diseases [Влияние технологий на возникновение инфекционных заболеваний]. Epidemiol, 1996, no. 18, pp. 4-9.
5. Iervolino M, Mancini B, Cristino S. Industrial cooling tower disinfection treatment to prevent legionella [Дезинфекция промышленных градирен для предотвращения заражения легионеллой]. International Journal of Environmental Research and Public Health, 2017, no. 14(10), p. 1125.
6. Walser S.M., Gerstner D.G., Brenner B. et al. Assessing the environmental health relevance of cooling towers - a systematic review of legionellosis outbreaks [Оценка влияния градирен на здоровье окружающей среды: систематический обзор вспышек легионеллеза]. International Journal of Hygiene and Environmental Health, 2014, no. 217, pp. 145-154.
7. Chien S. H., Hsieh M.K., Li H. et al. Pilot-scale cooling tower to evaluate corrosion, scaling, and biofouling control strategies for cooling system makeup water [Экспериментальная градирня для оценки методов борьбы с коррозией, накипеобразованием и биообрастанием в подпиточной воде системы охлаждения]. Review of Scientific Instruments, 2012, no. 83, p. 024101.
8. Chien S. H., Chowdhury I., Hsieh M. K. et al. Control of biological growth in recirculating cooling systems using treated secondary effluent as makeup water with monochloramine [Контроль биологического роста в рециркуляционных системах охлаждения с использованием очищенных вторичных сточных вод в качестве подпиточной воды с добавлением монохлорамина]. Water Research, 2012, no. 46, pp. 6508-6518.
9. Feofanov Yu. A., Kudryavcev A. V. Biofilm formation and development in biofilters under different wastewater supply regimes. Vestnik grazhdanskih inzhenerov, 2025, no. 1(108), pp. 76-84. (In Russ.). doi: 10.23968/1999-5571-2025-22-1-76-84
10. Carducci A., Verani M., Battistini R. Legionella in industrial cooling towers: Monitoring and control strategies [Легионелла в промышленных градирнях: стратегии мониторинга и контроля]. Letters in Applied Microbiology, 2010, no. 50, pp. 24-29.
11. Springston J. P., Yocavitch L. Existence and control of Legionella bacteria in building water systems: a review [Распространение бактерий Legionella в системах водоснабжения зданий и борьба с ними: обзор]. Journal of Occupational and Environmental Hygiene, 2017, no. 14, pp. 124-134.
12. Kim B. R., Anderson J. E., Mueller S. A. et al. Literature review - efficacy of various disinfectants against Legionella in water systems [Обзор литературы: эффективность различных дезинфицирующих средств против легионеллы в системах водоснабжения]. Water Research, 2002, no. 36, pp. 4433-4444.
13. Strokova V., Urmanova Ch., Kalatozi G. et al. Method to improve the efficiency of volumetric hydrophobisation of protective layers of building structures [Способ повышения эффективности объемной гидрофобизации защитных слоев строительных конструкций]. Architecture and Engineering, 2024, vol. 9, no. 4, pp. 99-108. doi: 10.23968/2500-0055-2024-9-4-99-108
14. Ngoc-Long T., Van-Phuc Ph., Morozov V. Investigating the corrosion initiation process in reinforced concrete structures under the impact of climate change [Исследование процесса начала коррозии в железобетонных конструкциях под влиянием изменений климата]. Architecture and Engineering, 2021, vol. 6, no. 2, pp. 37-44. doi:10.23968/2500-0055-2021-6-2-37-44.
15. Gurdin R. A., Vasil'ev V. M., Feofanov Yu. A. et al. Correlation between the productivity of silver and copper ions and their effect on the organoleptic characteristics of swimming pool water. Vestnik grazhdanskih inzhenerov, 2024, no. 1(102), pp. 65-72. (In Russ.). doi: 10.23968/1999-5571-2024-21-1-65-72
16. Costa R.D.F.S., Barbosa M.L.S, Silva F.J.G. et al. Study of the chlorine influence on the corrosion of three steels to be used in water treatment municipal facilities [Исследование влияния хлора на коррозию трех видов стали, используемых на муниципальных водоочистных сооружениях]. Materials (Basel), 2023, no. 16(6), p. 2514.
17. Gurdin R. A., Vasil'ev V. M., Feofanov Yu. A. et al. Nanochasticy serebra v tekhnologicheskom processe vodopodgotovki fontanov. Promyshlennoe i grazhdanskoe stroitel'stvo, 2024, no. 3, pp. 72-78. (In Russ.). doi: 10.33622/0869-7019.2024.03.72-78
18. Gao L., Zhang A. Copper-instigated modulatory cell mortality mechanisms and progress in oncological treatment investigations [Механизмы гибели клеток, запускаемые медью, и прогресс в исследованиях методов лечения онкологических заболеваний]. Front Immunol, 2023, no. 2;14, p. 1236063 - For citation: Gurdin R. A., Belyaev A. N., Feofanov Yu. A., Shabalin V. V., Chernikov N. A. The Use of Silver and Copper Colloid for Disinfection of Water in Cooling Towers. Promyshlennoe i grazhdanskoe stroitel'stvo [Industrial and Civil Engineering], 2026, no. 3, pp. 84-90. (In Russ.). doi: 10.33622/0869-7019.2026.03.84-90
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